Bromidocarbonyl{(1S,2S)-N-[2-(dicyclohexylphosphanyl)ethylidenyl]-N′-[2-(diphenylphosphanyl)ethyl]-1,2-diphenylethane-1,2-diamine}iron(II) tetraphenylborate
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چکیده
منابع مشابه
Microsolvation of the dicyanamide anion: [N(CN)(2)(-)](H(2)O)n (n = 0-12).
Photoelectron spectroscopy is combined with ab initio calculations to study the microsolvation of the dicyanamide anion, N(CN)(2)(-). Photoelectron spectra of [N(CN)(2)(-)](H2O)n (n = 0-12) have been measured at room temperature and also at low temperature for n = 0-4. Vibrationally resolved photoelectron spectra are obtained for N(CN)(2)(-), allowing the electron affinity of the N(CN)2 radical...
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The title compound, C24H20NSSe+.C24H20B-, exhibits disorder (S/Se scrambling) of the chalcogen sites within the S-N-Se triad. Similar disorder was observed in the bromide salt [Aucott, Bailey, Elsegood, Gilby, Holmes, Kelly, Papageorgiou & Pedron-Haba (2004). New J. Chem. pp. 959-966]. The S-N and Se-N bond lengths are 1.6735 (15) and 1.8045 (14) A, respectively. Whereas the chalcogens in the b...
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The photodissociation dynamics of I2 ~CO2)n(n54 – 16) clusters excited at 780 nm have been studied with femtosecond photoelectron spectroscopy ~FPES!. The range of cluster sizes spans the uncaged and fully-caged product limits for this reaction. We observe time scales for a variety of processes in these clusters, including dissociation of the I2 2 chromophore, solvation of the I fragment, the o...
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^ d jw0j (w0) + ^ d jw1j (w1) 2 + E(jwj + 1) = d 0 (w0) + d 0 (w1) 2 so d 0 obeys the average law (without conservation). Proof.[of Theorem 19] Note the d 0 constructed in Theorem 18 is generally not conservative. We will parallel Theorem 4, by constructing a slothful two-sided quasipolynomially precise cover. The construction of a conservative cover from a slothful cover preserves two-sided qu...
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ژورنال
عنوان ژورنال: IUCrData
سال: 2017
ISSN: 2414-3146
DOI: 10.1107/s2414314617004527